Decomposition reactions in CaCu3Ti4O12 ceramics(6)

2838JournaloftheAmericanCeramicSociety—Adamsetal.

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Vol.89,No.9

grainboundaryregionsofCCTOceramics.Thisshouldprovidemoreinformationregardingthecomposition–electricalpropertyrelationshipsinCCTOceramics.

References

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S.Y.Chung,I.L.D.Kim,andS.J.L.Kang,‘‘StrongNon-LinearCurrent–VoltageBehaviourinPerovskite-DerivativeCalciumCopperTitanate,’’Nat.Ma-ter.,3[11]774–8(2004).3

D.C.Sinclair,T.B.Adams,F.D.Morrison,andA.R.West,‘‘CaCu3Ti4O12:One-StepInternalBarrierLayerCapacitor,’’Appl.Phys.Lett.,80[12]2153–5(2002).4

T.B.Adams,D.C.Sinclair,andA.R.West,‘‘GiantBarrierLayerCapaci-tanceEffectsinCaCu3Ti4O12Ceramics,’’Adv.Mater.,14[18]1321–2(2002).

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R.K.Grubbs,E.L.Venturini,P.G.Clem,J.J.Richardson,B.A.Tuttle,andG.A.Samara,‘‘DielectricandMagneticPropertiesofFe-andNb-DopedCaCu3Ti4O12,’’Phys.Rev.,B72,104111(2005).6

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J.Li,M.A.Subramanian,H.D.Rosenfeld,C.Y.Jones,B.H.Toby,andA.W.Sleight,‘‘CluestotheGiantDielectricConstantofCaCu3Ti4O12intheDefectStructureofSrCu3Ti4O12,’’Chem.Mater.,16,5223–5(2004).8

T.B.Adams,D.C.Sinclair,andA.R.West,‘‘CharacterisationofGrainBoundaryImpedancesinFine-andCoarse-GrainedCaCu3Ti4O12Ceramics,’’Phys.Rev.B,73,0941241–9(2006).9

T.B.Adams,D.C.Sinclair,andA.R.West,‘‘TheIn uenceofProcessingConditionsontheElectricalPropertiesofCaCu3Ti4O12Ceramics,’’J.Am.Ceram.Soc.,inpress.10

M.A.SubramanianandA.W.Sleight,‘‘ACu3Ti4O12andACu3Ru4O12Per-ovskites:HighDielectricConstantsandValencyDegeneracy,’’SolidStateSci.,4,347–51(2002).11

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